FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W2000673359> ?p ?o ?g. }

• W2000673359 endingPage "276" @default.
• W2000673359 startingPage "263" @default.
• W2000673359 abstract "In order to synthesize penta- and hexa-gonal platinum(II) metallocycles, bidentate ligands such as iminopyridines (L) have been prepared and characterized. The (2-pyridyl)CHNR1 and (2-pyridyl)CH2NCR1R2 ligands react with Zeise's salt to afford directly the pentagonal chelates PtCl2L. Their structure and the cis-stereo-chemistry were shown by the usual spectroscopic methods and for cis-PtCl2[C5H4NCH2NC(CH3)C6H4OH],H2O by an X-ray diffraction study. On the other hand, the (2-pyridyl)(CH2)2NCR1R2 ligands do not afford the expected hexagonal metallocycles; instead, after complexation at the nitrogen atom of the imine they give rise to the (2-pyridyl)ethylamine complex formed after hydrolysis of the coordinated ligands. Complexes trans-[ethylene][(2-pyridyl)(CH2)2NCR1R2]PtCl2 represent when R1 is estradiol a model for “cytotoxic with delayed activity”. Afin de synthétiser des métallocycles penta- ou hexa-gonaux du platine(II), des ligands bidentates iminopyridines (L) ont été préparés et caractérisés. Les ligands du type (pyridiyl-2)CHNR1 et (pyridyl-2)CH2NCR1R2 réagissent directement avec le sel de Zeise pour donner les chélates pentagonaux de formule PtCl2L Leurs structures et la stéréochimie cis sont démontrées par leurs caractéristiques spectroscopiques et grâce à une étude réalisée par diffraction des rayons X. Par contre les ligands (pyridyl-2)(CH2)2NCR1R2 ne conduisent pas aux métallocycles à six chainons attendus mais au complexe de la (pyridyl-2) éthylamine résultant de l'hydrolyse du ligand, coordiné dans un premier temps par l'azote de l'imine. Les complexes trans-[éthylène][(pyridyl-2)(CH2)2NCR1R2]PtCl2 constituent, lorsque R1 esst l'estradiol, un modèle “d'estrogène toxique à effet retard”." @default.
• W2000673359 created "2016-06-24" @default.
• W2000673359 creator A5001302945 @default.
• W2000673359 creator A5010378253 @default.
• W2000673359 creator A5045960811 @default.
• W2000673359 creator A5082650768 @default.
• W2000673359 date "1986-09-01" @default.
• W2000673359 modified "2023-09-25" @default.
• W2000673359 title "Complexation d'iminopyridines par le sel de zeise: voie d'access a des conjugues estradiol-cis-dichloro platine. Etude structure du complexe cis-PtCl2[C5H4NCH2NC(CH3)C6H4OH],H2O" @default.
• W2000673359 cites W1491392751 @default.
• W2000673359 cites W1598154278 @default.
• W2000673359 cites W1964785613 @default.
• W2000673359 cites W1966823695 @default.
• W2000673359 cites W1970177576 @default.
• W2000673359 cites W1987495665 @default.
• W2000673359 cites W2040009502 @default.
• W2000673359 cites W2064344222 @default.
• W2000673359 cites W2093110754 @default.
• W2000673359 doi "https://doi.org/10.1016/0022-328x(86)80303-5" @default.
• W2000673359 hasPublicationYear "1986" @default.
• W2000673359 type Work @default.
• W2000673359 sameAs 2000673359 @default.
• W2000673359 citedByCount "17" @default.
• W2000673359 countsByYear W20006733592013 @default.
• W2000673359 countsByYear W20006733592015 @default.
• W2000673359 crossrefType "journal-article" @default.
• W2000673359 hasAuthorship W2000673359A5001302945 @default.
• W2000673359 hasAuthorship W2000673359A5010378253 @default.
• W2000673359 hasAuthorship W2000673359A5045960811 @default.
• W2000673359 hasAuthorship W2000673359A5082650768 @default.
• W2000673359 hasConcept C115624301 @default.
• W2000673359 hasConcept C155647269 @default.
• W2000673359 hasConcept C161790260 @default.
• W2000673359 hasConcept C178516000 @default.
• W2000673359 hasConcept C185592680 @default.
• W2000673359 hasConcept C518104683 @default.
• W2000673359 hasConcept C55493867 @default.
• W2000673359 hasConcept C71240020 @default.
• W2000673359 hasConcept C8010536 @default.
• W2000673359 hasConceptScore W2000673359C115624301 @default.
• W2000673359 hasConceptScore W2000673359C155647269 @default.
• W2000673359 hasConceptScore W2000673359C161790260 @default.
• W2000673359 hasConceptScore W2000673359C178516000 @default.
• W2000673359 hasConceptScore W2000673359C185592680 @default.
• W2000673359 hasConceptScore W2000673359C518104683 @default.
• W2000673359 hasConceptScore W2000673359C55493867 @default.
• W2000673359 hasConceptScore W2000673359C71240020 @default.
• W2000673359 hasConceptScore W2000673359C8010536 @default.
• W2000673359 hasIssue "2" @default.
• W2000673359 hasLocation W20006733591 @default.
• W2000673359 hasOpenAccess W2000673359 @default.
• W2000673359 hasPrimaryLocation W20006733591 @default.
• W2000673359 hasRelatedWork W1965563766 @default.
• W2000673359 hasRelatedWork W1987198665 @default.
• W2000673359 hasRelatedWork W2005486536 @default.
• W2000673359 hasRelatedWork W2016410175 @default.
• W2000673359 hasRelatedWork W2068141960 @default.
• W2000673359 hasRelatedWork W2074259103 @default.
• W2000673359 hasRelatedWork W2078697690 @default.
• W2000673359 hasRelatedWork W2090464385 @default.
• W2000673359 hasRelatedWork W2112921483 @default.
• W2000673359 hasRelatedWork W2148741250 @default.
• W2000673359 hasVolume "312" @default.
• W2000673359 isParatext "false" @default.
• W2000673359 isRetracted "false" @default.
• W2000673359 magId "2000673359" @default.
• W2000673359 workType "article" @default.