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- W2000678207 abstract "Solutions of heterocyclic analogues of 2-styrylnaphthalene (2-St-N), with benzo[b]thiophene and benzo[b]furan groups replacing the 2-naphthyl group, exhibit emission anomalies similar to those reported for 2-St-N, the most prominent one being a variation of the emission spectra with the excitation wavelength. The exciplexes formed when emission is quenched by N,N-dimethylaniline (DMA) show a smaller variation of their emission maxima. Ground-state rotamers may be responsible for the anomalies. The lifetimes of regular fluorescence in toluene are ≤ 2 ns, and our equipment did not allow to determine whether or not the decay is mono-exponential. Exciplex lifetimes in toluene are 20-30 ns. The triplets (λ 500-520 nm) are characterized by short lifetimes (180-190 ns) and appear to have substantial contributions from twisted configurations." @default.
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- W2000678207 date "1984-12-19" @default.
- W2000678207 modified "2023-09-26" @default.
- W2000678207 title "Conformational Equilibria intrans-1,2-Diarylethylenes Manifested in their Emission in Solution. Part VI. Heterocyclic Analogues, their Triplets and Exciplexes" @default.
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- W2000678207 doi "https://doi.org/10.1002/hlca.19840670830" @default.
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