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• W2000686806 abstract "Single crystals of monohydrated $L$-asparagine have been grown from aqueous solutions using $mathrm{Mn}{mathrm{Cl}}_{2}$ as doping material. Electron paramagnetic resonance (EPR) was used to determine the incorporation sites of ${mathrm{Mn}}^{2+}$ ions in the crystal structure. Depending on small $pmathrm{H}$ changes and crystal growth kinetics in the aqueous solutions, ${mathrm{Mn}}^{2+}$ ions are incorporated in two chemically distinct sites in asparagine crystals. The first shows isotropic six-line hyperfine-split EPR spectra, whereas the second shows anisotropic multiple line splitting due to ${mathrm{Mn}}^{2+}$ fine structure $(S=5∕2)$ and hyperfine interaction $(I=5∕2)$. Angular dependencies of the ${mathrm{Mn}}^{2+}$ EPR spectra in three mutually perpendicular crystal planes were measured and analyzed. The results are discussed in terms of the metal incorporation site symmetry in the crystal structure of monohydrated $L$-asparagine." @default.
• W2000686806 created "2016-06-24" @default.
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• W2000686806 date "2007-03-21" @default.
• W2000686806 modified "2023-09-25" @default.
• W2000686806 title "Two different incorporation sites of manganese in single-crystalline monohydrated<mml:math xmlns:mml=http://www.w3.org/1998/Math/MathML display=inline><mml:mi>L</mml:mi></mml:math>-asparagine studied by electron paramagnetic resonance" @default.
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• W2000686806 doi "https://doi.org/10.1103/physrevb.75.104205" @default.
• W2000686806 hasPublicationYear "2007" @default.
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