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- W2000687984 abstract "The present study experimentally demonstrated clathrate hydrate formation in the systems of (methane + water + each of the three methylcyclohexanone isomers, i.e., 2-methylcyclohexanone, 3-methylcyclohexanone, and 4-methylcyclohexanone) and measured the first data of the quadruple (water rich liquid + hydrate + methylcyclohexanone rich liquid + methane rich vapor) equilibrium pressure and temperature conditions in these systems over the temperatures from T=273 K to T=281 K. In the three systems with methylcyclohexanone, the measured equilibrium pressure at each given temperature is ∼1.3 MPa lower than that in a structure-I hydrate forming (methane + water) system without any methylcyclohexanone, which suggests the formation of structure-H hydrates with methylcyclohexanones as large-molecule guest substances. Among the three systems, 3-methylcyclohexanone provides the highest equilibrium pressure, and 2-methylcyclohexanone, the lowest." @default.
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- W2000687984 date "2003-12-01" @default.
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- W2000687984 title "Clathrate hydrate formation in (methane+water+methylcyclohexanone) systems: the first phase equilibrium data" @default.
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- W2000687984 doi "https://doi.org/10.1016/j.jct.2003.08.010" @default.
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