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- W2000688804 abstract "Abstract The synthesis of 1, 4-cyclohexadiene (1, 4-CHD) by the metathesis of 1, 4-alkadiene (1, 4-AD) was investigated using a continuous-flow system over a CsNO 3 -Re 2 O 7 -Al 2 O 3 catalyst in liquid phase at atmospheric pressure. The effects of 1, 4-AD structure on the reactivity and reaction behavior were also studied. The reaction behaviors of 1, 4-hexadiene (1, 4-HD) and 1, 4-octadiene (1, 4-OD) were almost the same, but that of 1, 4-pentadiene (1, 4-PD) differed widely. The reactivity of 1, 4-ADs decreased in the following sequence: 1, 4-HD > 1, 4-OD > l, 4-PD. The order was mainly governed by the reactivity of carbenes. In the metathesis of 1, 4-PD, degenerative meta-thesis, which does not contribute to the conversion, occurred more than with other 1, 4-ADs, and this led to the lowest reactivity and a different reaction behavior. 1, 4-CHD could be obtained from either 1, 4-AD with fairly good selectivity and yield per pass at mild reaction conditions. It is considered that the 1, 4-CHD synthesis by metathesis provides a new and effective synthetic process." @default.
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- W2000688804 date "1987-03-01" @default.
- W2000688804 modified "2023-10-10" @default.
- W2000688804 title "Metathesis of 1, 4-alkadienes over a CsNO3-Re2O7-Al2O3 catalyst" @default.
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- W2000688804 doi "https://doi.org/10.1016/0304-5102(87)80083-4" @default.
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