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• W2000691227 abstract "The existence of rotational conformers in solutions of 1,5-bis[dialkylaminophenyl]-1,4-pentadien-3-one (I) was investigated by infrared, absorption and fluorescence spectroscopy. Comparison was made with 2,5-bis{[4-(dialkylamino)phenyl]-methylene}-cyclopentanone (II) and 2,6-bis{[4-(dialkylamino)phenyl]-methylene}-cyclohexanone (III) which may be considered as rigidified analogues of I. The study in organic solvents revealed that two different conformers coexisted in solutions of I. They differ by rotation about the carbonyl-carbon quasi-single bond and, according to spectroscopic data and AM1 calculations, could be cis, cis and cis, trans isomers, the latter being found in much larger proportions." @default.
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• W2000691227 date "2000-01-01" @default.
• W2000691227 modified "2023-10-18" @default.
• W2000691227 title "Spectrophotometric evidence for the existence of rotamers in solutions of some ketocyanine dyes" @default.
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• W2000691227 doi "https://doi.org/10.1016/s1010-6030(99)00213-0" @default.
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