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• W2000693658 startingPage "162" @default.
• W2000693658 abstract "In this study the interaction between new benzimidazole molecules, 2-(2-nitrophenyl)-1H-benzimidazole (NB) and N-benzoyl-2-(2-nitrophenyl)-benzimidazole (BNB), with dsDNA and ssDNA was assessed at pH 7.4. Using differential pulse voltammetry at glassy carbon electrode, both molecules were electrochemically reduced due to the presence of a nitro group in their structures. When DNA was added to the solution, the electrochemical signal of NB and BNB decreased and shifted to more negative potentials. The interaction mode was electrostatic when ionic strength was low. Under this condition DNA-nitro complexes were characterized and binding constant values of 8.22 x 10(4)M(-1) and 3.08 x 10(6)M(-1) for NB and BNB with dsDNA were determined. On the other hand, only NB was able to interact when a high concentration of NaCl was used. Finally, a glassy carbon electrode modified with carbon nanotubes and DNA was tested in order to determine the nitrocompound in solution. The electrochemical reduction of the nitrocompound adsorbed on GCE/CHIT-CNT/DNA was used as an analytical signal. Using 10 min as accumulation time, a linear dependence was observed between 20 and 80 microM nitrocompound concentrations and the electrode response. Detection and quantification limits in the range of microM were determined." @default.
• W2000693658 created "2016-06-24" @default.
• W2000693658 creator A5054340486 @default.
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• W2000693658 date "2010-10-01" @default.
• W2000693658 modified "2023-10-10" @default.
• W2000693658 title "Electrochemistry of interaction of 2-(2-nitrophenyl)-benzimidazole derivatives with DNA" @default.
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• W2000693658 doi "https://doi.org/10.1016/j.bioelechem.2010.02.002" @default.
• W2000693658 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/20304709" @default.
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