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- W2000695928 abstract "Abstract Dithiocroconate (anion of 4-cyclopentene-1,2,3-trione-4,5-dimercapto) was investigated by resonance Raman spectroscopy. Excitation in resonance with the first allowed transition at ca. 465 nm causes the enhancement of virtually all the observed modes, indicating the delocalized nature of the chromophore. On the other hand, the fact that all the enhanced modes are totally symmetrical indicates that in contrast to its parent ion (croconate), dithiocroconate derives its resonance enhancement from the Franck-Condon mechanism. Comparison of the Raman frequency values for croconate and dithiocroconate reveals that for the latter, electron delocalization in the ring, although it is present, is not as symmetrical as in the former." @default.
- W2000695928 created "2016-06-24" @default.
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- W2000695928 date "1990-01-01" @default.
- W2000695928 modified "2023-09-26" @default.
- W2000695928 title "The resonance Raman effect of dithiocroconate" @default.
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- W2000695928 doi "https://doi.org/10.1016/0022-2860(90)80312-8" @default.
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