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- W2000696462 abstract "A novel chainlike coordination polymer [Cu(II)(2,2'-bipy)(H(2)O)(2)Al(OH)(6)Mo(6)O(18)](n)()(n)()(-), formed from a heteropolyanion [Al(OH)(6)Mo(6)O(18)](3)(-) as a building unit and a copper(II) complex fragment, [Cu(II)(2,2'-bipy)(H(2)O)(2)](2+), as a linker, provides the first example of an extended structure based on an Anderson type of polyanion and a transition metal complex with organic ligand. The intra- and interchain O-H.O hydrogen-bonding interactions are seemingly responsible for the spiral shape of this chain. Crystal data: triclinic space group Ponemacr;, a = 11.2253(18) A, b = 14.5194(17) A, c = 15.2672(10) A, alpha = 112.191(8) degrees, beta = 106.693(9) degrees, gamma = 93.916(13) degrees, and Z = 2." @default.
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- W2000696462 date "2003-09-17" @default.
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- W2000696462 title "Formation of a Spiral-Shaped Inorganic−Organic Hybrid Chain, [Cu<sup>II</sup>(2,2‘-bipy)(H<sub>2</sub>O)<sub>2</sub>Al(OH)<sub>6</sub>Mo<sub>6</sub>O<sub>18</sub>]<i><sub>n</sub></i><i><sup>n</sup></i><sup>-</sup>: Influence of Intra- and Interchain Supramolecular Interactions" @default.
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- W2000696462 doi "https://doi.org/10.1021/ic034581f" @default.
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