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- W2000698887 abstract "Abstract After excitation into the S 1 (nπ*) ← absorption, butynal decomposes into CO and propyne (H 3 CCCH). Emission lifetimes, photoproduct quantum yields, and phosphorescence quantum yields were measured in the pressure range 0.25–2 Torr at room temperature using excitation energies between 26620 (0-0 transition) and 33300 cm −1 . Based on these results and on those of the propynal (HCCCHO) dynamics previously reported. a photodissociation mechanism for butynal is proposed which features dissociation from the hot S 0 ground state by a concerted reaction." @default.
- W2000698887 created "2016-06-24" @default.
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- W2000698887 date "1982-12-01" @default.
- W2000698887 modified "2023-10-18" @default.
- W2000698887 title "Photochemical decay of butynal (H3CCCCHO) in the gas phase following S1(nπ*) ← S0 excitation" @default.
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- W2000698887 doi "https://doi.org/10.1016/0301-0104(82)85179-3" @default.
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