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• W2000699382 abstract "Abstract The ESR spectrum of isolated Cr 3+ ions and nearest-neighbour Cr 3+ ion pairs in SrLaGaO 4 and SrLaAlO 4 single crystals have been studied at X-band. A nearly isotropic, single line of isolated Cr 3+ ions was observed for g = 1.980(2) in both materials. The zero-field splitting was small, therefore all allowed Cr 3+ transitions nearly overlapped one another. For the nearest-neighbour Cr 3+ ion pairs the ESR spectrum could only be observed for the S = 2 state, because broadening mechanisms did not affect this level. The coefficients of the isotropic exchange interaction J were determined from temperature dependencies of line intensity. The angular dependencies of ESR lines allowed the determination of the anisotropic exchange interaction constants. The following values have been found: J = 5.4(2)cm −1 , g = 1.980(2), |D E | = 137(2) × 10 −4 cm −1 , |E E | = 22(2) × 10 −4 cm −1 and J = 5.4(2) cm −1 , g = 1.980(2), |D E | = 196(2) × 10 −4 cm −1 , |E E | = 32(1) × 10 −4 cm −1 for SrLaGaO 4 and SrLaAlO 4 crystals, respectively." @default.
• W2000699382 created "2016-06-24" @default.
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• W2000699382 date "1997-03-01" @default.
• W2000699382 modified "2023-10-17" @default.
• W2000699382 title "Electron spin resonance study of isolated Cr3+ ions and Cr3+ ion pairs in SrLaGaO4 and SrLaAlO4 single crystals" @default.
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• W2000699382 doi "https://doi.org/10.1016/s0304-8853(96)00630-0" @default.
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