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• W2000700054 abstract "Because of the Ti(3+) defects responsibility for dissociative adsorption of water onto TiO(2) surfaces and due to the hydroxyls influence on the biological behavior of titanium, controlling the Ti(3+) surface defects density by means of low-temperature vacuum annealing is proposed to improve the bone/implant interactions. Experiments have been carried out on Ti-6Al-4V alloys exhibiting a porous surface generated primarily by chemical treatment. XPS investigations have shown that low-temperature vacuum annealing can create a controlled number of Ti(3+) defects (up to 21% Ti(3+)/Ti(4+) at 573 K). High Ti(3+) defect concentration is linked to surface porosity. Such surfaces, exhibiting high hydrophilicity and microporosity, would confer to titanium biomaterials a great ability to interact with surrounding proteins and cells and hence would favor the bone anchorage of as-treated implants." @default.
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• W2000700054 date "2002-11-01" @default.
• W2000700054 modified "2023-10-07" @default.
• W2000700054 title "Ti4+ to Ti3+ Conversion of TiO2 Uppermost Layer by Low-Temperature Vacuum Annealing: Interest for Titanium Biomedical Applications" @default.
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• W2000700054 doi "https://doi.org/10.1006/jcis.2002.8623" @default.
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