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- W2000704932 abstract "Abstract The 11B and 19F nuclear quadrupole couplings in F3BNHx(CH3)3−x compounds were measured in the solid state by quadrupole perturbed nuclear magnetic resonance of boron and time-differential, perturbed angular distribution of the γ radiation of excited fluorine nuclei. The coupling constants are independent of the number of methyl substituents within experimental error both in the case of boron ( e 2 qQ h = 80 ± 8 kHz ) and in the case of fluorine ( e 2 gQ h = 30.0 ± 0.5 MHz ). Similarly, there is no change of the asymmetry F3BNH(CH3)2, a boron asymmetry parameter of 0.30 ± 0.05 was found. Earlier results on the nitrogen quadrupole couplings in F3BNHxR3−x, and the nitrogen and boron couplings in H3BNHxR3−x compounds, extended by the present findings, provide a clear picture of the chemical bonding in these compounds, especially the donor-acceptor character and the ionicity of the boron-nitrogen bond." @default.
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- W2000704932 date "1986-09-01" @default.
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- W2000704932 title "Boron, nitrogen, and fluorine nuclear quadrupole coupling and the electronic structure of the boron-nitrogen single bond" @default.
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- W2000704932 doi "https://doi.org/10.1016/0022-2364(86)90081-8" @default.
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