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- W2000706146 abstract "Abstract A general method for the formation of fused dihydroazepine derivatives from 1‐sulfonyl‐1,2,3‐triazoles bearing a tethered diene is reported. The process involves an intramolecular cyclopropanation of an α‐imino rhodium(II) carbenoid, leading to a transient 1‐imino‐2‐vinylcyclopropane intermediate which rapidly undergoes a 1‐aza‐Cope rearrangement to generate fused dihydroazepine derivatives in moderate to excellent yields. The reaction proceeds with similar efficiency on gram scale. The use of catalyst‐free conditions leads to the formation of a novel [4.4.0] bicyclic heterocycle." @default.
- W2000706146 created "2016-06-24" @default.
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- W2000706146 date "2014-07-15" @default.
- W2000706146 modified "2023-10-18" @default.
- W2000706146 title "Expedient Synthesis of Fused Azepine Derivatives Using a Sequential Rhodium(II)-Catalyzed Cyclopropanation/1-Aza-Cope Rearrangement of Dienyltriazoles" @default.
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- W2000706146 doi "https://doi.org/10.1002/anie.201405356" @default.
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