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• W2000707068 abstract "Ion/molecule reactions of ‘bare’ FeO+ with linear and branched aliphatic alcohols have been examined by Fourier-transform ion-cyclotron resonance mass spectrometry. Depending on the chain length of the alcohol, three different types of reactions can be distinguished: (i) Oxidation of the alcohols in the α-positions, to yield the corresponding carbonyl-Fe+ complexes, involves an initial OH bond activation of the alcohol resulting in the formation of ROFe+OH as the central intermediate. (ii) The formation of Fe(OH), concomitant by loss of the corresponding neutral alkenes, competes with the generation of neutral OFeOH and a carbocation R+. These couples point to the existence of an intracomplex acid-base equilibrium and are connected with each other by a proton transfer from either acid to the other, e.g. i-C3H + OFeOH⇄C3H6 + Fe(OH). The process is driven by the Lewis acidity of FeO+ and starts with the abstraction of a hydroxide anion from the alcohol. (iii) For longer alcohols, e.g. pentanol, functionalization of non-activated CH bonds which are remote from the O functionality is observed. Here, the OH group of the alcohol serves as an anchor, which directs the reactive metal-oxide cation toward a particular site of the hydrocarbon chain." @default.
• W2000707068 created "2016-06-24" @default.
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• W2000707068 date "1996-02-07" @default.
• W2000707068 modified "2023-10-16" @default.
• W2000707068 title "Gas-Phase Reactions of Aliphatic Alcohols with ‘Bare’ FeO⁺" @default.
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• W2000707068 doi "https://doi.org/10.1002/hlca.19960790113" @default.
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