FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W2000710587> ?p ?o ?g. }

• W2000710587 endingPage "10196" @default.
• W2000710587 startingPage "10189" @default.
• W2000710587 abstract "Infrared reflection−absorption spectra in the CH2 out-of-plane wagging (ω(CH2)) vibration region were measured for ethylene (C2H4) adsorbed on Ag(110) as well as on the oxygen-induced p(n×1) reconstructed surfaces of Ag(110) (n = 6, 4, 3, and 2) at 80 K. C2H4 on Ag(110) gives a main peak at 955 cm-1, whereas C2H4 on p(n×1)O−Ag(110) (n = 6, 4, 3) gives rise to a 972−976 cm-1 band (α-state) at low exposures, shifting it to 966−970 cm-1 (β-state) at saturation coverage. The adsorption behavior of C2H4 on the p(n×1) surfaces (n = 6, 4, 3) are explained by assuming that (i) adsorption sites exist between the added Ag−O rows parallel to the 〈001〉 direction; (ii) adsorption sites on both sides of the added Ag−O row form a special pair; (iii) at lower coverages one of the pair is selectively occupied, resulting in the formation of the α state. At higher coverages, where all the sites for the α state are occupied, C2H4 begins to occupy the other site of the pair, forming the β state. Thermal desorption spectra were measured for C2H4 on Ag(110) as well as on the atomic oxygen reconstructed surfaces. The desorption on Ag(110) consists of a state with a peak temperature = 110 K, whereas those on p(n×1)O−Ag(110) (n = 6, 4, 3) consist of two states, corroborating the adsorption model on these surfaces derived from the IR spectra. The desorption temperatures at the α states are found to increase as follows: 130 K (p(6×1)) < 145 K (p(4×1)) < 160 K (p(3×1)), which indicates that the stability of the α states increases with the surface coverage of the atomic oxygen. C2H4 on p(2×1)O−Ag(110) does not take either the α or the β state, but exists in an irregular state, giving a broad feature centered at 970 cm-1 for the ω(CH2) band region. This can be explained by considering that the space between the added Ag−O rows on p(2×1)O−Ag(110) is too narrow to deliver the adsorption sites for the α and β states." @default.
• W2000710587 created "2016-06-24" @default.
• W2000710587 creator A5023672333 @default.
• W2000710587 creator A5042355949 @default.
• W2000710587 creator A5043129708 @default.
• W2000710587 creator A5014896243 @default.
• W2000710587 date "1999-10-30" @default.
• W2000710587 modified "2023-09-27" @default.
• W2000710587 title "Adsorption Structures of Ethylene on Ag(110) and Atomic Oxygen Precovered Ag(110) Surfaces: Infrared Reflection−Absorption and Thermal Desorption Spectroscopic Studies" @default.
• W2000710587 cites W1968288909 @default.
• W2000710587 cites W1968722898 @default.
• W2000710587 cites W1979101910 @default.
• W2000710587 cites W1990836280 @default.
• W2000710587 cites W1994873768 @default.
• W2000710587 cites W2012391663 @default.
• W2000710587 cites W2023906010 @default.
• W2000710587 cites W2025289916 @default.
• W2000710587 cites W2026014570 @default.
• W2000710587 cites W2056325229 @default.
• W2000710587 cites W2072957801 @default.
• W2000710587 cites W2087751429 @default.
• W2000710587 cites W2088499637 @default.
• W2000710587 doi "https://doi.org/10.1021/jp992025u" @default.
• W2000710587 hasPublicationYear "1999" @default.
• W2000710587 type Work @default.
• W2000710587 sameAs 2000710587 @default.
• W2000710587 citedByCount "21" @default.
• W2000710587 countsByYear W20007105872013 @default.
• W2000710587 countsByYear W20007105872016 @default.
• W2000710587 countsByYear W20007105872019 @default.
• W2000710587 crossrefType "journal-article" @default.
• W2000710587 hasAuthorship W2000710587A5014896243 @default.
• W2000710587 hasAuthorship W2000710587A5023672333 @default.
• W2000710587 hasAuthorship W2000710587A5042355949 @default.
• W2000710587 hasAuthorship W2000710587A5043129708 @default.
• W2000710587 hasConcept C113196181 @default.
• W2000710587 hasConcept C114614502 @default.
• W2000710587 hasConcept C119824511 @default.
• W2000710587 hasConcept C120665830 @default.
• W2000710587 hasConcept C121332964 @default.
• W2000710587 hasConcept C125287762 @default.
• W2000710587 hasConcept C1276947 @default.
• W2000710587 hasConcept C147789679 @default.
• W2000710587 hasConcept C150394285 @default.
• W2000710587 hasConcept C153642686 @default.
• W2000710587 hasConcept C155916967 @default.
• W2000710587 hasConcept C158355884 @default.
• W2000710587 hasConcept C159985019 @default.
• W2000710587 hasConcept C161790260 @default.
• W2000710587 hasConcept C162711632 @default.
• W2000710587 hasConcept C178790620 @default.
• W2000710587 hasConcept C185592680 @default.
• W2000710587 hasConcept C192562407 @default.
• W2000710587 hasConcept C2778597550 @default.
• W2000710587 hasConcept C2781059571 @default.
• W2000710587 hasConcept C33923547 @default.
• W2000710587 hasConcept C43617362 @default.
• W2000710587 hasConcept C4839761 @default.
• W2000710587 hasConcept C540031477 @default.
• W2000710587 hasConcept C55493867 @default.
• W2000710587 hasConcept C9930424 @default.
• W2000710587 hasConceptScore W2000710587C113196181 @default.
• W2000710587 hasConceptScore W2000710587C114614502 @default.
• W2000710587 hasConceptScore W2000710587C119824511 @default.
• W2000710587 hasConceptScore W2000710587C120665830 @default.
• W2000710587 hasConceptScore W2000710587C121332964 @default.
• W2000710587 hasConceptScore W2000710587C125287762 @default.
• W2000710587 hasConceptScore W2000710587C1276947 @default.
• W2000710587 hasConceptScore W2000710587C147789679 @default.
• W2000710587 hasConceptScore W2000710587C150394285 @default.
• W2000710587 hasConceptScore W2000710587C153642686 @default.
• W2000710587 hasConceptScore W2000710587C155916967 @default.
• W2000710587 hasConceptScore W2000710587C158355884 @default.
• W2000710587 hasConceptScore W2000710587C159985019 @default.
• W2000710587 hasConceptScore W2000710587C161790260 @default.
• W2000710587 hasConceptScore W2000710587C162711632 @default.
• W2000710587 hasConceptScore W2000710587C178790620 @default.
• W2000710587 hasConceptScore W2000710587C185592680 @default.
• W2000710587 hasConceptScore W2000710587C192562407 @default.
• W2000710587 hasConceptScore W2000710587C2778597550 @default.
• W2000710587 hasConceptScore W2000710587C2781059571 @default.
• W2000710587 hasConceptScore W2000710587C33923547 @default.
• W2000710587 hasConceptScore W2000710587C43617362 @default.
• W2000710587 hasConceptScore W2000710587C4839761 @default.
• W2000710587 hasConceptScore W2000710587C540031477 @default.
• W2000710587 hasConceptScore W2000710587C55493867 @default.
• W2000710587 hasConceptScore W2000710587C9930424 @default.
• W2000710587 hasIssue "46" @default.
• W2000710587 hasLocation W20007105871 @default.
• W2000710587 hasOpenAccess W2000710587 @default.
• W2000710587 hasPrimaryLocation W20007105871 @default.
• W2000710587 hasRelatedWork W2008857883 @default.
• W2000710587 hasRelatedWork W2034142270 @default.
• W2000710587 hasRelatedWork W2056054481 @default.
• W2000710587 hasRelatedWork W2066438544 @default.
• W2000710587 hasRelatedWork W2068347131 @default.
• W2000710587 hasRelatedWork W2074919545 @default.
• W2000710587 hasRelatedWork W2079150189 @default.

• next