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- W2000711295 abstract "Tributylzinnhydrid reduziert das Addukt 4 von HBr an Bullvalen (1) zu einem Gemisch der Olefine 3, 6, 7, 8 und 9. Die zu den Olefinen 3, 8 und 9 führenden radikalischen Umlagerungen werden über Cyclopropylcarbinylradikale formuliert. — Bullvalendibromid (5) ergibt unter ähnlichen Bedingungen 6, 7, 8, 9 und zusätzlich das Brom-Eliminierungsprodukt 2. Der Anteil an 2 steigt mit steigender Temperatur und mit fallender Konzentration an Tributylzinnhydrid. Radical Rearrangements in Some Bicyclic Systems The adduct 4 of HBr and bullvalene (1) is reduced by tri-n-butyltin hydride to a mixture of the olefines 3, 6, 7, 8 and 9. The free radical rearrangements leading to 3, 8 and 9 are formulated as going through cyclopropylcarbinyl radicals. — Under similar conditions the reaction of bullvalenedibromide (5) gives 6, 7, 8, 9 and the elimination product 2. The proportion of 2 increases with rising temperature and with decreasing concentration of tri-n-butyltin hydride." @default.
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- W2000711295 date "1971-06-01" @default.
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- W2000711295 title "Radikalische Umlagerungen in einigen bicyclischen Systemen" @default.
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- W2000711295 doi "https://doi.org/10.1002/cber.19711040639" @default.
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