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- W2000713358 abstract "Explicit expressions for local surfaces and local compositions in mixtures obtained from the quasi-chemical approach of Guggenheim are presented and their relations with empirical expressions discussed. The treatment is greatly simplified by introducing well-defined, non-random factors. A method is proposed for the solution of the set of non-linear equations arising from the quasi-chemical approach. Detailed equations are given for the case of binary and ternary systems. The extension of the general approach in terms of groups is discussed. The quasi-chemical expressions for the local surface fractions are combined with the formalism of the New Flory Theory in order to account for non-randomness in polymer solutions. The resulting expressions are applied to experimental data of the systems carbon tetrachloride—polypropylene oxide, chloroform—polypropylene oxide and benzene—polyisobutylene." @default.
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- W2000713358 title "The quasi-chemical approach for non-randomness in liquid mixtures. Expressions for local surfaces and local compositions with an application to polymer solutions" @default.
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- W2000713358 doi "https://doi.org/10.1016/0378-3812(80)80043-4" @default.
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