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- W2000716808 abstract "Dipotassium octaoxodecahydroxotetratellurate, K2[Te4O8(OH)10], has been prepared hydrothermally in acidic medium under autogenous pressure. It crystallizes in space group P21/c of the monoclinic system with Z=2 in a cell of dimensions a=5.592(1) Å, b=8.283(2) Å, c=16.255(3) Å, and β=99.62(3)°. The outstanding feature of the structure is a tetrameric [Te4O8(OH)10]2– anion built up from edge and corner sharing TeO6 octahedra. These anions and K+ cations are held together by electrostatic interactions and by hydrogen bonds. The compound decomposes in two steps at 350 and 420 °C, corresponding to a water and an oxygen loss, respectively, and affording the mixed valence oxide K2TeVI3TeIVO12." @default.
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- W2000716808 date "2001-02-01" @default.
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- W2000716808 title "K2[Te4O8(OH)10]: synthesis, crystal structure and thermal behavior" @default.
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- W2000716808 doi "https://doi.org/10.1016/s1293-2558(00)01121-3" @default.
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