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• W2000717576 startingPage "1591" @default.
• W2000717576 abstract "Two MOFs of [SrII(5-NO2-BDC)(H2O)6] (1) and [BaII(5-NO2-BDC)(H2O)6] (2) have been synthesized in water using alkaline earth metal salts and the rigid organic ligand 5-NO2-H2BDC. The compounds were characterized by elemental analysis, infrared spectrum, thermal analysis, and X-ray crystallography. Crystal structure analyses have shown that the two complexes are isostructural as evidenced by IR spectra and TG-DTA. Both compounds present three-dimensional frameworks built up from infinite chains of edge-sharing twelve-membered rings through O–H···O hydrogen bonds. The specific heat capacities of the title complexes have been determined by an improved RD496-III microcalorimeter with the values of (109.29 ± 0.693) J mol−1 K−1 and (81.162 ± 0.858) J mol−1 K−1 at 298.15 K, and the molar enthalpy changes of the formation reactions of complexes at 298.15 K were calculated as (4.897 ± 0.008) kJ mol−1 and (2.617 ± 0.009) kJ mol−1, respectively." @default.
• W2000717576 created "2016-06-24" @default.
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• W2000717576 date "2008-08-01" @default.
• W2000717576 modified "2023-10-14" @default.
• W2000717576 title "Two Three-Dimensional Metal-Organic Frameworks Constructed from Alkaline Earth Metal Cations (Sr and Ba) and 5-Nitroisophthalicacid – Synthesis, Charaterization, and Thermochemistry" @default.
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• W2000717576 doi "https://doi.org/10.1002/zaac.200800047" @default.
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