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- W2000717688 abstract "The two common ionic forms of iron have quite different character with respect to polarizability. The Fe(III) is considered a harder Pearson acid than Fe(II). The octasubstituted C-methyl-calix[4]resorcinarene (1) with its carboxylate arms and aromatic rings can form both “hard” and “soft” ion binding sites, respectively. In this work the interactions of Fe(III) and Fe(II) ions with 1 were investigated by photoluminescence (PL) and quantum-chemical methods. The results suggest that Fe(II) ions form complexes with 1 favorably through cation−π interactions, while the complexation of Fe(III) ions is mainly based on the chelate formation with the carboxylate moieties of the resorcinarene molecule. This observation makes 1 and its analogues promising candidates to be used in chemical sensors as special redox-sensitive host molecules." @default.
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- W2000717688 date "2003-04-18" @default.
- W2000717688 modified "2023-10-17" @default.
- W2000717688 title "Complex Formation of Fe(II) and Fe(III) Ions with Octafunctionalized C-Methyl-calix[4]resorcinarene Possessing −OCH2COOH (K) Moieties" @default.
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- W2000717688 doi "https://doi.org/10.1021/jp027051y" @default.
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