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- W2000721189 abstract "Abstract Aza(bisoxazoline) was easily immobilized on siliceous mesocellular foam (MCF) in a systematic approach. It was found that silanol precapping, linker group flexibility, ligand loading, and silanol postcapping were important factors to consider in optimizing silica‐supported aza(bisoxazoline) catalysts. The optimized MCF‐supported aza(bisoxazoline)‐copper catalyst offered the same enantioselectivity as its homogeneous counterpart, and excellent recyclability. The heterogenized catalyst showed a much higher chemoselectivity in a short reaction time. The heterogenized aza(bisoxazoline)‐copper(I) catalyst was successfully applied to a circulating flow‐type packed bed reactor with excellent productivity and enantioselectivity. The circulating flow‐type reactor was found to be very useful for gas‐generating catalytic reactions such as cyclopropanation reaction." @default.
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- W2000721189 date "2008-05-30" @default.
- W2000721189 modified "2023-10-18" @default.
- W2000721189 title "Siliceous Mesocellular Foam-Supported Aza(bisoxazoline)-Copper Catalysts" @default.
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- W2000721189 doi "https://doi.org/10.1002/adsc.200700388" @default.
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