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• W2000722011 abstract "Ag electrodeposits were grown on a polycrystalline Ag cathode at either 0.01 or 1 mA cm-2 from aqueous 5 × 10-3 M Ag2SO4 + 10-2 M H2SO4 + 0.5 M Na2SO4, in the absence and presence of different amounts of thiourea (TU). The cathode/solution interface evolution in a quasi-bidimensional electrochemical cell was followed with a video microscope imaging system. From TU-free solution a nodular morphology at 0.01 mA cm-2 and a branched morphology at 1 mA cm-2 were observed. At 0.01 mA cm-2 the presence of TU drove the interface motion to a stable roughness regime by suppressing the nucleation and growth of instabilities. Accordingly, the characteristics of the growth front were consistent with the predictions of the Edwards−Wilkinson equation for the interface motion. At 1 mA cm-2, those electrodeposits grown in the presence of TU showed a decrease in both the nucleation and growth rates of instabilities, although they were not fully suppressed." @default.
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• W2000722011 date "1999-01-29" @default.
• W2000722011 modified "2023-10-08" @default.
• W2000722011 title "Smoothening Mechanism of Thiourea on Silver Electrodeposition. Real Time Imaging of the Growth Front Evolution" @default.
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• W2000722011 doi "https://doi.org/10.1021/la9806092" @default.
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