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- W2000724143 abstract "The thermodynamic interactions in anionically synthesized poly(styrene-block-ferrocenyldimethylsilane) (SF) copolymers were examined using birefringence, small-angle X-ray and neutron scattering (SAXS and SANS). We show that birefringence detection of the order−disorder transition is possible in colored samples provided the wavelength of the incident beam is in the tail of the absorption spectrum. The location of the order−disorder transition was confirmed by SAXS. The temperature dependence of the Flory−Huggins parameter, χ, of SF copolymers, determined by SAXS, is similar in magnitude to that between polystyrene and polyisoprene chains. We find that χ is independent of block copolymer composition (within experimental error). We also demonstrate that the neutron scattering length densities of styrene and ferrocenyldimethylsilane moieties are identical due to a surprising cancellation of factors related to density and atomic composition." @default.
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- W2000724143 date "2002-08-30" @default.
- W2000724143 modified "2023-09-27" @default.
- W2000724143 title "Thermodynamic Interactions in Organometallic Block Copolymers: Poly(styrene-<i>b</i><i>lock</i>-ferrocenyldimethylsilane)" @default.
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- W2000724143 doi "https://doi.org/10.1021/ma020647z" @default.
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