Matches in SemOpenAlex for { <https://semopenalex.org/work/W2000724377> ?p ?o ?g. }
- W2000724377 endingPage "3582" @default.
- W2000724377 startingPage "3572" @default.
- W2000724377 abstract "Conventional sodium cations (Na+) in sulfonated polyester ionomers were replaced with ammonium-based ionic liquid counterions. Counterion dynamics were measured by dielectric spectroscopy and linear viscoelastic response via oscillatory shear. Ion exchange from sodium counterions to ionic liquid counterions such as tetramethylammonium and tetrabutylammonium showed an order of 104 increase in conductivity compared with sodium counterions, primarily attributed to weaker ionic interactions that lower the glass transition temperature. Electrode polarization was used in conjunction with the 1953 Macdonald model to determine the number density of conducting counterions and their mobility. Conductivity and mobility exhibit Vogel−Fulcher−Tammann (VFT) temperature dependences and both increased with counterion size. Conducting counterion concentrations showed Arrhenius temperature dependences, with activation energy reduced as counterion size increased. When ether−oxygen was incorporated into the mobile cation structure, self-solvating ability notably increased the conducting ion concentration. Weakened ion pairing interactions prove favorable for fundamental design of single-ion conductors for actuators, as ionic liquid counterions can provide both larger and faster strains, required by such electro-active devices." @default.
- W2000724377 created "2016-06-24" @default.
- W2000724377 creator A5004070698 @default.
- W2000724377 creator A5022274838 @default.
- W2000724377 creator A5060989553 @default.
- W2000724377 creator A5070151668 @default.
- W2000724377 date "2011-04-08" @default.
- W2000724377 modified "2023-10-12" @default.
- W2000724377 title "Counterion Dynamics in Polyester−Sulfonate Ionomers with Ionic Liquid Counterions" @default.
- W2000724377 cites W1949231392 @default.
- W2000724377 cites W1965127033 @default.
- W2000724377 cites W1966891910 @default.
- W2000724377 cites W1967031237 @default.
- W2000724377 cites W1970380021 @default.
- W2000724377 cites W1974284830 @default.
- W2000724377 cites W1975141243 @default.
- W2000724377 cites W1979883644 @default.
- W2000724377 cites W1979958074 @default.
- W2000724377 cites W1981923548 @default.
- W2000724377 cites W1982479518 @default.
- W2000724377 cites W1989982913 @default.
- W2000724377 cites W1990627763 @default.
- W2000724377 cites W2000168732 @default.
- W2000724377 cites W2005039510 @default.
- W2000724377 cites W2006318126 @default.
- W2000724377 cites W2019743961 @default.
- W2000724377 cites W2020723966 @default.
- W2000724377 cites W2025070646 @default.
- W2000724377 cites W2026489676 @default.
- W2000724377 cites W2031903478 @default.
- W2000724377 cites W2034768112 @default.
- W2000724377 cites W2037612519 @default.
- W2000724377 cites W2046599847 @default.
- W2000724377 cites W2052551423 @default.
- W2000724377 cites W2053750299 @default.
- W2000724377 cites W2053940673 @default.
- W2000724377 cites W2062466245 @default.
- W2000724377 cites W2067132576 @default.
- W2000724377 cites W2068176385 @default.
- W2000724377 cites W2074009695 @default.
- W2000724377 cites W2076261840 @default.
- W2000724377 cites W2076451041 @default.
- W2000724377 cites W2082868504 @default.
- W2000724377 cites W2085332871 @default.
- W2000724377 cites W2088490755 @default.
- W2000724377 cites W2092227202 @default.
- W2000724377 cites W2092885209 @default.
- W2000724377 cites W2100274645 @default.
- W2000724377 cites W2104411200 @default.
- W2000724377 cites W2104579769 @default.
- W2000724377 cites W2107245011 @default.
- W2000724377 cites W2116049919 @default.
- W2000724377 cites W2135344399 @default.
- W2000724377 cites W2144529765 @default.
- W2000724377 cites W2147050578 @default.
- W2000724377 cites W2155409190 @default.
- W2000724377 cites W2163779749 @default.
- W2000724377 cites W2172861685 @default.
- W2000724377 cites W2317273030 @default.
- W2000724377 cites W2326203395 @default.
- W2000724377 cites W2327155795 @default.
- W2000724377 cites W2328925659 @default.
- W2000724377 cites W3100150232 @default.
- W2000724377 cites W4211127612 @default.
- W2000724377 cites W4238219156 @default.
- W2000724377 cites W585924654 @default.
- W2000724377 doi "https://doi.org/10.1021/ma102547q" @default.
- W2000724377 hasPublicationYear "2011" @default.
- W2000724377 type Work @default.
- W2000724377 sameAs 2000724377 @default.
- W2000724377 citedByCount "81" @default.
- W2000724377 countsByYear W20007243772012 @default.
- W2000724377 countsByYear W20007243772013 @default.
- W2000724377 countsByYear W20007243772014 @default.
- W2000724377 countsByYear W20007243772015 @default.
- W2000724377 countsByYear W20007243772016 @default.
- W2000724377 countsByYear W20007243772017 @default.
- W2000724377 countsByYear W20007243772018 @default.
- W2000724377 countsByYear W20007243772019 @default.
- W2000724377 countsByYear W20007243772020 @default.
- W2000724377 countsByYear W20007243772021 @default.
- W2000724377 countsByYear W20007243772022 @default.
- W2000724377 countsByYear W20007243772023 @default.
- W2000724377 crossrefType "journal-article" @default.
- W2000724377 hasAuthorship W2000724377A5004070698 @default.
- W2000724377 hasAuthorship W2000724377A5022274838 @default.
- W2000724377 hasAuthorship W2000724377A5060989553 @default.
- W2000724377 hasAuthorship W2000724377A5070151668 @default.
- W2000724377 hasConcept C138679309 @default.
- W2000724377 hasConcept C145148216 @default.
- W2000724377 hasConcept C147789679 @default.
- W2000724377 hasConcept C159467904 @default.
- W2000724377 hasConcept C17525397 @default.
- W2000724377 hasConcept C178790620 @default.
- W2000724377 hasConcept C179104552 @default.
- W2000724377 hasConcept C185592680 @default.
- W2000724377 hasConcept C188027245 @default.
- W2000724377 hasConcept C2182769 @default.