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• W2000724782 abstract "Uniaxial elongation and compression data of linear and branched polymer melts as well as of rubbers are analyzed with respect to their nonlinear strain measure. This is found to be the result of two contributions: (1) affine orientation of network strands, and (2) isotropic strand extension. Network strand extension is caused by an increasing restriction of lateral movement of polymer chains due to deformation, and is modelled by a molecular stress function f, which in the tube concept of Doi and Edwards is the inverse of the relative tube diameter. At small strains, f2 is found to be linear in the average stretch for melts as well as for rubbers, which corresponds to an affine deformation of the tube. At large strains, melts show maximum molecular tension depending on the degree of long-chain branching, while rubbers show maximum extensibility." @default.
• W2000724782 created "2016-06-24" @default.
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• W2000724782 date "1993-04-01" @default.
• W2000724782 modified "2023-09-27" @default.
• W2000724782 title "The nonlinear strain measure of polymer melts and rubbers: A unifying approach" @default.
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• W2000724782 doi "https://doi.org/10.1002/masy.19930680109" @default.
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