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- W2000724982 abstract "Catalytic properties of the metal-organic framework Cr-MIL-101 in solvent-free cycloaddition of CO2 to epoxides to produce cyclic carbonates using tetrabutylammonium bromide as co-catalyst have been explored under mild reaction conditions (8 bar CO2, 25 0C). Styrene and propylene carbonates were formed with high yields (95% and 82%, respectively). Catalytic performance of Cr-MIL-101 was compared with other MOFs: Fe-MIL-101, Zn-MOF-5 and HKUST-1. The catalytic properties of different quaternary ammonium bromides, Cr-MIL-101 as well as PW12/Cr-MIL-101 composite material have been assessed in oxidative carboxylation of styrene in the presence of both tert-butyl hydroperoxide and H2O2 as oxidants at 8–100 bar CO2 and 25–80 0C with selectivity to styrene carbonate up to 44% at 57% substrate conversion." @default.
- W2000724982 created "2016-06-24" @default.
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- W2000724982 date "2013-01-01" @default.
- W2000724982 modified "2023-10-16" @default.
- W2000724982 title "Synthesis of cyclic carbonates from epoxides or olefins and CO2 catalyzed by metal-organic frameworks and quaternary ammonium salts" @default.
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- W2000724982 doi "https://doi.org/10.1016/s2095-4956(13)60017-0" @default.
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