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- W2000728770 abstract "MoS 2 intercalated with Mn, Co, Ni, and Ru species, prepared from single layer MoS 2 dispersions in water, were studied by x-ray absorption spectroscopy. M K-edge EXAFS results (M = Mn, Co, Ni) are consistent with an alternating MoS 2 -M(OH) 2 layered structure. For the Mn and Co intercalates the MoS 2 layers were found to be very similar to that of the parent crystalline MoS 2 with trigonal prismatic coordination of the Mo atoms. For the Ni and Ru intercalates, Mo K edge EXAFS revealed structural rearrangement of MoS 2 layers similar to that observed for MoS 2 single layers, with octahedral coordination of Mo. S K edge XANES spectra reveal that the rearrangement is coupled with a change in the electronic structure of the S atoms in the matrix. These changes can be associated with charge transfer between host and guest layers. In addition, SO 4 2- and Mo 6+ were detected in some of the intercalated materials, presumably due to exposure to air, suggesting that transition metal intercalation may increase the susceptibility of the MoS 2 layers to oxidation." @default.
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- W2000728770 date "1997-04-01" @default.
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- W2000728770 title "XAFS Study of MoS<sub>2</sub>Intercalation Compounds" @default.
- W2000728770 doi "https://doi.org/10.1051/jp4:19972136" @default.
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