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- W2000730391 abstract "The stereoselectivity of baker's yeast in the reduction of ethyl 3-oxopentanoate was shifted towards the corresponding (R)-hydroxy ester by sugar, heat treatment and allyl alcohol. The highest enantiomeric excesses obtained with baker's yeast with a good reduction capacity, 92–97%, were achieved by combining allyl alcohol and sugar; heat treatment did not increase the stereoselectivity further. With the use of this technique, ethyl (R)-3-hydroxyhexanoate, >99% ee, and ethyl (S)-4-chloro-3-hydroxybutanoate, 82–90% ee, were produced from the corresponding esters, and for the first time an excess of the (R)-enantiomer of ethyl 3-hydroxybutanoate was obtained with ordinary baker's yeast." @default.
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- W2000730391 date "1999-02-01" @default.
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- W2000730391 title "Baker's yeast: improving the d-stereoselectivity in reduction of 3-oxo esters" @default.
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- W2000730391 doi "https://doi.org/10.1016/s0957-4166(99)00025-7" @default.
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