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- W2000732983 abstract "Illuminated with 450 W high pressure mercury lamp (HPML), the oxidation of aromatic aldehydes was investigated with molecular oxygen in the presence of Co(II)[meso-tetra(benzoyloxy-phenyl) porphyrin] (CoTBCOPP). The oxygen uptake was measured during the reaction process. Under the mild condition (30°C, 1 atm O2), the oxidation reactions occurred without consumption of reducing agent. It was observed that CoTBCOPP could catalyze the oxidation of aromatic aldehydes by reversibly binding molecular oxygen. The effects of the concentrations of catalyst and substrate in the oxidation reaction system were studied, meanwhile the factor of solvents was discussed in detail. The induction period was greatly shortened by raising the temperature of oxidation system or adding hydrogen dioxide. However, low dioxygen absorbed and the long induction period were obtained when imidazole was added as the fifth ligand." @default.
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- W2000732983 date "1999-11-01" @default.
- W2000732983 modified "2023-09-28" @default.
- W2000732983 title "Photocatalytic oxidation of aromatic aldehydes with Co(II)tetra-(benzoyloxyphenyl)porphyrin and molecular oxygen" @default.
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- W2000732983 doi "https://doi.org/10.1016/s1381-1169(99)00144-2" @default.
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