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• W2000733462 abstract "The sodium rhodate NaRh2O4 was synthesized for the first time and characterized by neutron and X-ray diffraction studies and measurements of magnetic susceptibility, specific heat, electrical resistivity, and the Seebeck coefficient. NaRh2O4 crystallizes in the CaFe2O4-type structure, which is comprised of a characteristic RhO6 octahedral network. The compound is metallic in nature, probably reflecting the 1:1 mixed valence character of Rh(III) and Rh(IV) in the network. For further studies of the compound, the Rh valence was varied significantly by means of an aliovalent substitution: the full-range solid solution between NaRh2O4 and CaRh2O4 was achieved and characterized as well. The metallic state was dramatically altered, and a peculiar magnetism developed in the low Na concentration range." @default.
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• W2000733462 date "2004-12-17" @default.
• W2000733462 modified "2023-10-09" @default.
• W2000733462 title "High-Pressure Synthesis, Crystal Structure Determination, and a Ca Substitution Study of the Metallic Rhodium Oxide NaRh₂O₄" @default.
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• W2000733462 doi "https://doi.org/10.1021/cm0483846" @default.
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