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• W2000733480 abstract "The synthesis of a unique isotope engineered system, double-wall carbon nanotubes with natural carbon outer and highly 13C enriched inner walls, is reported from isotope enriched fullerenes encapsulated in single-wall carbon nanotubes (SWCNTs). The material allows the observation of the D line of the highly defect-free inner tubes that can be related to a curvature induced enhancement of the electron-phonon coupling. Ab initio calculations explain the inhomogeneous broadening of inner tube Raman modes due to the distribution of different isotopes. Nuclear magnetic resonance shows a significant contrast of the isotope enriched inner SWCNTs compared to other carbon phases and provides a macroscopic measure of the inner tube mass content. The high curvature of the small diameter inner tubes manifests in an increased distribution of the chemical shift tensor components." @default.
• W2000733480 created "2016-06-24" @default.
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• W2000733480 date "2005-06-27" @default.
• W2000733480 modified "2023-10-15" @default.
• W2000733480 title "Isotope Engineering of Carbon Nanotube Systems" @default.
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• W2000733480 doi "https://doi.org/10.1103/physrevlett.95.017401" @default.
• W2000733480 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/16090655" @default.
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