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• W2000738245 abstract "The reaction of allene with complexes of the type (β-diketonato)Rh(C2H4)2 at temperatures between −30 and +20°, gives RhIII derivatives of formula (β-diketonato)Rh(C3H4)4, in which an allene tetramer is bonded to rhodium by two π-allylic groups. The molecular structures of these complexes were determined on the basis of the chemical behaviour, IR and NMR spectra, and, for one of them, also by X-ray examination. The reaction of (Acac)Rh(C2H4)2 with allene at −78° yields new rhodium(III) derivatives containing the 3,4-dimethylenerhodacyclopentane moiety. These are precursors of the bis(π-allylic) complexes. The mechanism of formation of the rhodium(III) complexes is briefly discussed." @default.
• W2000738245 created "2016-06-24" @default.
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• W2000738245 date "1975-01-01" @default.
• W2000738245 modified "2023-09-23" @default.
• W2000738245 title "The reaction of allene with β-diketonatorhodium(I) complexes: Formation of bis(π-allylic) complexes of rhodium(III) and of rhodacyclopentane derivatives" @default.
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• W2000738245 doi "https://doi.org/10.1016/s0022-328x(00)88776-8" @default.
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