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• W2000738847 abstract "Photodissociation of acetonitrile (CH3CN) condensed, physisorbed on Au(111), and chemisorbed on Pt(111), has been studied at the C(1s) and N(1s) edges in H+ yield and/or in total positive ion yield. The H+ yield C(1s) absorption experiment on the condensed acetonitrile shows a selective fragmentation of the C–H bond at the C 1s→π*CH3 excitation, that is still observed when acetonitrile is physisorbed on Au(111) and chemisorbed on Pt(111). Transitions to the π*C≡N state give rise to unselective fragmentations, which are strongly quenched by charge transfer from the substrate when acetonitrile is chemisorbed on Pt(111). The π⊥*C≡N level that plunges into the Pt(111) is the most affected and vanishes in the total ion yield measurement. The quenching is weaker on the π∥*C≡N which is parallel to the surface, and thus is less hybridized with the metal than the π⊥*C≡N. For acetonitrile physisorbed on Au(111), the influence of the surface is limited to the quenching of the desorption of the heaviest outgoing fragments." @default.
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• W2000738847 date "2000-01-08" @default.
• W2000738847 modified "2023-10-01" @default.
• W2000738847 title "Core-induced photofragmentation of acetonitrile adsorbed on Au(111) and Pt(111)" @default.
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• W2000738847 doi "https://doi.org/10.1063/1.480724" @default.
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