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- W2000741696 abstract "The Raman spectrum of ${mathrm{Ti}}_{2}$${mathrm{O}}_{3}$ exhibits seven modes as predicted for the corundum structure. The persistence of all seven of these modes above the semiconductor-metal transition temperature indicates no space-group change on going through the phase transition. The ${A}_{1g}$ mode at 269 ${mathrm{cm}}^{ensuremath{-}1}$ (300 ifmmode^circelsetextdegreefi{}K) exhibits a significant frequency change (about 16%) and a large intensity increase relative to the other modes in the temperature range of the semiconductor-metal transition. These results are interpreted in terms of electronic and structural changes during the phase transition." @default.
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- W2000741696 modified "2023-10-18" @default.
- W2000741696 title "Raman Study of the Semiconductor-Metal Transition in<mml:math xmlns:mml=http://www.w3.org/1998/Math/MathML display=inline><mml:mrow><mml:msub><mml:mrow><mml:mi mathvariant=normal>Ti</mml:mi></mml:mrow><mml:mrow><mml:mn>2</mml:mn></mml:mrow></mml:msub></mml:mrow></mml:math><mml:math xmlns:mml=http://www.w3.org/1998/Math/MathML display=inline><mml:mrow><mml:msub><mml:mrow><mml:mi mathvariant=normal>O</mml:mi></mml:mrow><mml:mrow><mml:mn>3</mml:mn></mml:mrow></mml:msub></mml:mrow></mml…" @default.
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- W2000741696 doi "https://doi.org/10.1103/physrevb.3.4253" @default.
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