Matches in SemOpenAlex for { <https://semopenalex.org/work/W2000743418> ?p ?o ?g. }
Showing items 1 to 86 of
86
with 100 items per page.
- W2000743418 endingPage "112" @default.
- W2000743418 startingPage "108" @default.
- W2000743418 abstract "Abstract Methylmagnesium bromide adds to trimethylsilyloctyne ( 1 ) in the presence of 10 mol% 1:0.67 nickel acetylacetonate‐trimethylaluminum to give a 9:1 mixture of alkenyl Grignard reagents 2a and 3a . This mixture reacts with water, deuterium oxide, formaldehyde, acetaldehyde, carbon dioxide, iodine, vinyl bromide or allyl bromide to give the expected products 2, 3b to 2, 3j . Nickel catalyzed carbometallation of 4 with MeMgBr followed by quenching with formaldehyde and desilylation gives trans, trans ‐farnesol ( 5c ). Nickel catalyzed addition of MeMgBr to 6a and 6b proceeds analogously, except that initially formed alkenyl Grignard reagents 7a and 7b isomerize completely to 8a and 8b which are stabilized by chelation. This carbometallation reaction allows the synthesis of both isomers of an allylic alcohol, such as 12 and 13 , from a common intermediate 2a ." @default.
- W2000743418 created "2016-06-24" @default.
- W2000743418 creator A5037700841 @default.
- W2000743418 creator A5041353759 @default.
- W2000743418 creator A5058607502 @default.
- W2000743418 date "1984-01-01" @default.
- W2000743418 modified "2023-10-17" @default.
- W2000743418 title "Nickel-Catalyzed Addition of Methylmagnesium Bromide to Alkynylsilanes. Stereospecific Synthesis of Tetrasubstituted Alkenes" @default.
- W2000743418 cites W1526426157 @default.
- W2000743418 cites W1966618034 @default.
- W2000743418 cites W1967839332 @default.
- W2000743418 cites W1971517981 @default.
- W2000743418 cites W1972434983 @default.
- W2000743418 cites W1983415829 @default.
- W2000743418 cites W1985178234 @default.
- W2000743418 cites W1995888989 @default.
- W2000743418 cites W1996832856 @default.
- W2000743418 cites W2009791783 @default.
- W2000743418 cites W2034588340 @default.
- W2000743418 cites W2042087173 @default.
- W2000743418 cites W2049365427 @default.
- W2000743418 cites W2057881998 @default.
- W2000743418 cites W2071693059 @default.
- W2000743418 cites W2071916144 @default.
- W2000743418 cites W2072192492 @default.
- W2000743418 cites W2107229170 @default.
- W2000743418 cites W2110223962 @default.
- W2000743418 cites W2116962389 @default.
- W2000743418 cites W2125675933 @default.
- W2000743418 cites W2162294606 @default.
- W2000743418 cites W2344528362 @default.
- W2000743418 cites W2950751907 @default.
- W2000743418 doi "https://doi.org/10.1002/ijch.198400019" @default.
- W2000743418 hasPublicationYear "1984" @default.
- W2000743418 type Work @default.
- W2000743418 sameAs 2000743418 @default.
- W2000743418 citedByCount "19" @default.
- W2000743418 countsByYear W20007434182015 @default.
- W2000743418 countsByYear W20007434182018 @default.
- W2000743418 crossrefType "journal-article" @default.
- W2000743418 hasAuthorship W2000743418A5037700841 @default.
- W2000743418 hasAuthorship W2000743418A5041353759 @default.
- W2000743418 hasAuthorship W2000743418A5058607502 @default.
- W2000743418 hasConcept C155647269 @default.
- W2000743418 hasConcept C161790260 @default.
- W2000743418 hasConcept C178790620 @default.
- W2000743418 hasConcept C185592680 @default.
- W2000743418 hasConcept C187921627 @default.
- W2000743418 hasConcept C2776300020 @default.
- W2000743418 hasConcept C2777595113 @default.
- W2000743418 hasConcept C2780161600 @default.
- W2000743418 hasConcept C2780616238 @default.
- W2000743418 hasConcept C40875361 @default.
- W2000743418 hasConcept C504270822 @default.
- W2000743418 hasConceptScore W2000743418C155647269 @default.
- W2000743418 hasConceptScore W2000743418C161790260 @default.
- W2000743418 hasConceptScore W2000743418C178790620 @default.
- W2000743418 hasConceptScore W2000743418C185592680 @default.
- W2000743418 hasConceptScore W2000743418C187921627 @default.
- W2000743418 hasConceptScore W2000743418C2776300020 @default.
- W2000743418 hasConceptScore W2000743418C2777595113 @default.
- W2000743418 hasConceptScore W2000743418C2780161600 @default.
- W2000743418 hasConceptScore W2000743418C2780616238 @default.
- W2000743418 hasConceptScore W2000743418C40875361 @default.
- W2000743418 hasConceptScore W2000743418C504270822 @default.
- W2000743418 hasIssue "2" @default.
- W2000743418 hasLocation W20007434181 @default.
- W2000743418 hasOpenAccess W2000743418 @default.
- W2000743418 hasPrimaryLocation W20007434181 @default.
- W2000743418 hasRelatedWork W1983433776 @default.
- W2000743418 hasRelatedWork W2030384680 @default.
- W2000743418 hasRelatedWork W2055360318 @default.
- W2000743418 hasRelatedWork W2088681451 @default.
- W2000743418 hasRelatedWork W2143170156 @default.
- W2000743418 hasRelatedWork W2245895065 @default.
- W2000743418 hasRelatedWork W2366418472 @default.
- W2000743418 hasRelatedWork W2390817463 @default.
- W2000743418 hasRelatedWork W2395978267 @default.
- W2000743418 hasRelatedWork W26328854 @default.
- W2000743418 hasVolume "24" @default.
- W2000743418 isParatext "false" @default.
- W2000743418 isRetracted "false" @default.
- W2000743418 magId "2000743418" @default.
- W2000743418 workType "article" @default.