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• W2000744182 abstract "Kinsenoside (1) and goodyeroside A (2), two naturally occurring stereoisomers with diverse biological activities, have been synthesized efficiently by a chemo-enzymatic approach with a total yield of 12.7%. The aglycones, (R)- and (S)-3-hydroxy-γ-butyrolactone, were prepared from D- and L-malic acid by a four-step chemical approach with a yield of 75%, respectively. These butyrolactones were then successfully glycosidated using β-D-glucosidase as a catalyst in a homogeneous organic-water system. Under the optimized enzymatic conditions, the yields of kinsenoside and goodyeroside A in the enzymatic steps both reached 16.8%." @default.
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• W2000744182 date "2014-10-22" @default.
• W2000744182 modified "2023-10-18" @default.
• W2000744182 title "Efficient Synthesis of Kinsenoside and Goodyeroside A by a Chemo-Enzymatic Approach" @default.
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• W2000744182 doi "https://doi.org/10.3390/molecules191016950" @default.
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