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- W2000748437 abstract "The thermal dissociation of methane in argon as carrier gas behind reflected shock waves was investigated. The reaction was followed by infrared (ir) emission of methane at 3.5 μ, by ir emission of formed species at wavelengths between 2.9 and 3.0 μ and by ultraviolet (uv) absorption of formed species at wave lengths between 2150 and 3000 . The dependence of the rate constants on temperature and pressure was observed at temperatures between 1850° and 2500°K, at total densities between 5.5×10−5 and 1.5×10−3 mole/cm3, and at 0.2%≤[CH4]0/[Ar]≤1%. In the pressure range investigated, k was found to depend on [Ar]. Below 2100°K, the reaction was observed to accelerate. A possible mechanism is discussed." @default.
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- W2000748437 date "1971-01-01" @default.
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- W2000748437 title "Thermal decomposition of methane behind reflected shock waves" @default.
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- W2000748437 doi "https://doi.org/10.1016/s0082-0784(71)80019-x" @default.
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