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- W2000748571 startingPage "2023" @default.
- W2000748571 abstract "Racemic methyl, iso-propyl, and tert-butyl ester derivatives of naproxen were treated with achiral LDA base to give the corresponding prochiral enolates 2-Li, 3-Li, and 4-Li. Protonation of these enolates with novel chiral proton sources (S)-10 and (S,S)-11, containing the α-phenylethylamino group, proceeded in a highly enantioselective manner. Saponification of enantioenriched ester derivatives 2–4 afforded naproxen, (S)-1, with no loss of enantiopurity." @default.
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- W2000748571 date "2003-03-01" @default.
- W2000748571 modified "2023-10-12" @default.
- W2000748571 title "Enantioselective protonation of prochiral enolates in the asymmetric synthesis of (S)-naproxen" @default.
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- W2000748571 doi "https://doi.org/10.1016/s0040-4039(03)00217-x" @default.
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