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- W2000749169 abstract "Crystal and molecular structures of four derivatives of d-mannose are described. Each could exist as either an open-chain Schiff base or as a glycosylamine in the solid state. The derivative formed upon reaction of d-mannose with hydroxylamine is an open-chain oxime, but those formed upon reaction with semicarbazide, aniline, and p-chloroaniline are glycosylamines. The oxime, which crystallizes as the syn-(E) isomer, has a fully extended carbon chain. The glycosylamines are all β-pyranoses. The packing arrangement of the oxime involves ‘head-to-tail’ hydrogen bonding. The semicarbazide derivative, which crystallizes as a dihydrate, features a hydrogen-bonded intramolecular bridge formed by the two water molecules and linking O-6 to the carbonyl oxygen atom. The packing arrangements of the aniline and p-chloroaniline derivatives differ from each other but are nevertheless closely related by similar hydrogen-bonding interactions." @default.
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- W2000749169 date "2000-06-01" @default.
- W2000749169 modified "2023-10-17" @default.
- W2000749169 title "Schiff bases or glycosylamines: crystal and molecular structures of four derivatives of d-mannose" @default.
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- W2000749169 doi "https://doi.org/10.1016/s0008-6215(00)00026-4" @default.
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