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- W2000751452 abstract "Abstract A cascade reaction that generates pyrrolo‐ and pyridoindoline motifs from isocyanide precursors under phase‐transfer conditions is described. This transformation proceeds at room temperature in the presence of a quaternary ammonium catalyst and base to generate functionalized products containing an all‐carbon quaternary stereocentre. Quantum chemical calculations demonstrated that intramolecular general acid catalysis plays a key accelerating role through stabilization of developing charge in the transition state, and that the reaction is best described as a 5‐endo dig cyclization, rather than an anionic 6π electrocyclization. Investigations employing chiral phase‐transfer catalysts have given promising selectivities to date." @default.
- W2000751452 created "2016-06-24" @default.
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- W2000751452 date "2014-02-12" @default.
- W2000751452 modified "2023-10-18" @default.
- W2000751452 title "Phase-Transfer-Catalysed Synthesis of Pyrroloindolines and Pyridoindolines by a Hydrogen-Bond-Assisted Isocyanide Cyclization Cascade" @default.
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- W2000751452 cites W1972813767 @default.
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- W2000751452 cites W1980155666 @default.
- W2000751452 cites W1982038325 @default.
- W2000751452 cites W1983098306 @default.
- W2000751452 cites W1985536417 @default.
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- W2000751452 cites W1987778120 @default.
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- W2000751452 cites W1998545592 @default.
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- W2000751452 cites W2020662063 @default.
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- W2000751452 cites W2027338515 @default.
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- W2000751452 doi "https://doi.org/10.1002/chem.201400192" @default.
- W2000751452 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/24523244" @default.
- W2000751452 hasPublicationYear "2014" @default.
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