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- W2000752648 abstract "Ideal tryptic peptides contain only a single basic residue, located at the C-terminus. Collisional fragmentation of their doubly- or triply-protonated ions generates doubly-charged y++ fragment ions with modest intensities. The size distribution of the y++ fragments, when averaged over many spectra, corresponds closely to the expectations from charge-directed backbone cleavage and a Coulomb-Boltzmann distribution of mobile protons. This observation should be helpful in developing mechanistic models for y++ formation." @default.
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- W2000752648 date "2011-12-20" @default.
- W2000752648 modified "2023-09-25" @default.
- W2000752648 title "Tryptic y++ Fragment Ion Distributions Are Guided by Coulombic Repulsion" @default.
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- W2000752648 doi "https://doi.org/10.1007/s13361-011-0293-7" @default.
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