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- W2000753363 abstract "Abstract In acetonitrile and tetrahydrofuran solutions, irradiation of [ReBr 6 ] 2− leads to the replacement of a bromide by a solvent molecule, followed at a much slower rate by the photosolvation of a second bromide. The quantum yield for the primary photosolvation is 0.013 in CH 3 CN. As an alternative to photolysis occurring through a doublet d–d excited state, it is suggested that excitation of the charge transfer bands may cause photodissociation, followed by coordination of a solvent molecule and reoxidation to the final product." @default.
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- W2000753363 date "2009-01-01" @default.
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- W2000753363 title "Photosolvation reactions of hexabromorhenate(IV)" @default.
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- W2000753363 doi "https://doi.org/10.1016/j.ica.2008.03.119" @default.
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