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- W2000754622 abstract "We show that, in contrast to normal polymers, a backbone nematic polymer, with dipoles along the chain axis, yields a dielectric susceptibility increased by a factor of the order of the degree of polymerization. We find (i) a purely exponential variation of susceptibility with temperature, partly reflecting the activiation of hairpin defects of chain conformations and (ii) nonlocality in the response, unlike isotropic polymers. The unusual form of these results suggests (macroscopic) dielectric experiments for finally observing hairpins and studying zero-field chain statistics." @default.
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- W2000754622 date "1987-01-26" @default.
- W2000754622 modified "2023-10-18" @default.
- W2000754622 title "Giant dielectric response and hairpins in polymeric nematics" @default.
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- W2000754622 doi "https://doi.org/10.1103/physrevlett.58.393" @default.
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