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- W2000758983 abstract "Variable temperature PMR spectra of the title compounds are analyzed in the −50 to +106° range. The limiting low-temperature spectrum of the methyl derivative shows that metal migration is retarded enough to identify individual nonequivalent configurations. The mode of metallotropic rearrangement for 5-(silyl)-cyclopentadiene appears to be either 1,2 or random cavorts. Prototropic rearrangement proceeds much slower becoming increasingly evident at and above +66°. The AA′BB′X pattern at the slow exchange limit and the infrared spectrum (in the 3000 cm−1 region) of 5-(silyl)cyclopentadiene are consistent with a “static” σ-type bond between the H3Si moiety and the unique carbon of the cyclopentadienyl ring." @default.
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- W2000758983 date "1973-04-01" @default.
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- W2000758983 title "Fluxional behavior of 5-(silyl)cyclopentadiene and 5-(silyl)methylcyclopentadiene (1,2-isomer mixture)" @default.
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- W2000758983 doi "https://doi.org/10.1016/s0022-328x(00)93508-3" @default.
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