Matches in SemOpenAlex for { <https://semopenalex.org/work/W2000760799> ?p ?o ?g. }
- W2000760799 endingPage "2174" @default.
- W2000760799 startingPage "2168" @default.
- W2000760799 abstract "A rational approach for the construction of multi-stranded artificial β-sheets based not on hydrogen bonding, but rather on π–π aromatic stacking, is presented. Using 4,6-dinitro-1,3-phenylenediamine units, rigid turns were designed that allow face-to-face π–π interactions between appended linear aromatic segments to be strong enough for folding in an organic solvent, but weak enough to prevent aggregation and precipitation. Solution and solid-state studies on a series of turn units showed that the desired degree of rigidity, resulting from hindered bond rotation, could be fine-tuned by the inclusion of additional methyl substituents on the aromatic rings. The high degree of preorganization afforded by these qualities further allowed the facile preparation of macrocyclic sheet structures from their noncyclic precursors. These macrocycles were shown to have slow internal dynamics and defined conformational preferences. Using this background, three- and five-stranded artificial β-sheets were synthesized and their folded conformations extensively characterized in solution by NMR. The solid-state structures of the three- and five-stranded sheets were also elucidated in the solid state by X-ray crystallography and confirmed intramolecular π–π aromatic stacking." @default.
- W2000760799 created "2016-06-24" @default.
- W2000760799 creator A5022649566 @default.
- W2000760799 creator A5032747366 @default.
- W2000760799 creator A5035014019 @default.
- W2000760799 creator A5056370756 @default.
- W2000760799 creator A5070599855 @default.
- W2000760799 date "2014-01-23" @default.
- W2000760799 modified "2023-10-15" @default.
- W2000760799 title "Aromatic Oligoamide β-Sheet Foldamers" @default.
- W2000760799 cites W1648880131 @default.
- W2000760799 cites W1838110516 @default.
- W2000760799 cites W1963731853 @default.
- W2000760799 cites W1965436903 @default.
- W2000760799 cites W1965953414 @default.
- W2000760799 cites W1966679473 @default.
- W2000760799 cites W1969885133 @default.
- W2000760799 cites W1975263049 @default.
- W2000760799 cites W1976483388 @default.
- W2000760799 cites W1977285911 @default.
- W2000760799 cites W1978314665 @default.
- W2000760799 cites W1980068946 @default.
- W2000760799 cites W1983583688 @default.
- W2000760799 cites W1984441668 @default.
- W2000760799 cites W1986326797 @default.
- W2000760799 cites W1989421448 @default.
- W2000760799 cites W1990973411 @default.
- W2000760799 cites W1994348785 @default.
- W2000760799 cites W1998667894 @default.
- W2000760799 cites W2001651299 @default.
- W2000760799 cites W2011269474 @default.
- W2000760799 cites W2014092160 @default.
- W2000760799 cites W2017764099 @default.
- W2000760799 cites W2018832019 @default.
- W2000760799 cites W2024777504 @default.
- W2000760799 cites W2033059953 @default.
- W2000760799 cites W2035172212 @default.
- W2000760799 cites W2039014196 @default.
- W2000760799 cites W2039811942 @default.
- W2000760799 cites W2042267577 @default.
- W2000760799 cites W2046004326 @default.
- W2000760799 cites W2048715736 @default.
- W2000760799 cites W2050653286 @default.
- W2000760799 cites W2050868331 @default.
- W2000760799 cites W2052658097 @default.
- W2000760799 cites W2053934133 @default.
- W2000760799 cites W2056104022 @default.
- W2000760799 cites W2057837553 @default.
- W2000760799 cites W2061203106 @default.
- W2000760799 cites W2061476247 @default.
- W2000760799 cites W2067667324 @default.
- W2000760799 cites W2082408021 @default.
- W2000760799 cites W2090241512 @default.
- W2000760799 cites W2093042977 @default.
- W2000760799 cites W2105245583 @default.
- W2000760799 cites W2109622685 @default.
- W2000760799 cites W2119038558 @default.
- W2000760799 cites W2130685678 @default.
- W2000760799 cites W2144296806 @default.
- W2000760799 cites W2153900826 @default.
- W2000760799 cites W2159164756 @default.
- W2000760799 cites W2161860927 @default.
- W2000760799 cites W2168798075 @default.
- W2000760799 cites W2169428497 @default.
- W2000760799 cites W2171108117 @default.
- W2000760799 cites W2180204534 @default.
- W2000760799 cites W2324187722 @default.
- W2000760799 cites W2324259686 @default.
- W2000760799 cites W2412210998 @default.
- W2000760799 cites W3021435911 @default.
- W2000760799 cites W4234803768 @default.
- W2000760799 cites W4248737905 @default.
- W2000760799 doi "https://doi.org/10.1021/ja412729s" @default.
- W2000760799 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/24422529" @default.
- W2000760799 hasPublicationYear "2014" @default.
- W2000760799 type Work @default.
- W2000760799 sameAs 2000760799 @default.
- W2000760799 citedByCount "81" @default.
- W2000760799 countsByYear W20007607992014 @default.
- W2000760799 countsByYear W20007607992015 @default.
- W2000760799 countsByYear W20007607992016 @default.
- W2000760799 countsByYear W20007607992017 @default.
- W2000760799 countsByYear W20007607992018 @default.
- W2000760799 countsByYear W20007607992019 @default.
- W2000760799 countsByYear W20007607992020 @default.
- W2000760799 countsByYear W20007607992021 @default.
- W2000760799 countsByYear W20007607992022 @default.
- W2000760799 countsByYear W20007607992023 @default.
- W2000760799 crossrefType "journal-article" @default.
- W2000760799 hasAuthorship W2000760799A5022649566 @default.
- W2000760799 hasAuthorship W2000760799A5032747366 @default.
- W2000760799 hasAuthorship W2000760799A5035014019 @default.
- W2000760799 hasAuthorship W2000760799A5056370756 @default.
- W2000760799 hasAuthorship W2000760799A5070599855 @default.
- W2000760799 hasBestOaLocation W20007607992 @default.
- W2000760799 hasConcept C107814960 @default.
- W2000760799 hasConcept C112887158 @default.
- W2000760799 hasConcept C119599485 @default.