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• W2000764134 abstract "In the present research, the temperature dependence of heat capacity Cp,m∘=f(T) of crystalline bis-(η6-cumene)chromium fulleride [(η6-PhCH(CH3)2)2Cr]+[C60]− has been measured between Т = (6 and 310) K in the precision adiabatic vacuum calorimeter and reported for the first time. Also, for the first time, the temperature dependence of EPR signal parameters of bis-(η6-cumene)chromium fulleride over the range from T = (120 to 290) K was investigated by electron paramagnetic resonance. In the interval from T = (196 to 240) K the reversible endothermic transformation was detected and its thermodynamic characteristics were estimated. This transformation was caused by dissociation of dimer (C60-)2 and formation of fulleride [(η6-PhCH(CH3)2)2Cr]+[C60]− during heating. The experimental results have been used to calculate the standard (р° = 0.1 MPa) thermodynamic functions Cp,m∘/R, ΔT1T2Hm∘/RT, ΔT1T2Sm∘/R, and Φm∘/R=ΔT1T2Sm∘/R-ΔT1T2Hm∘/RT (where R is the universal gas constant) for dimeric fulleride over the range from T → (0 to 196) K and for monomeric complex [(η6-PhCH(CH3)2)2Cr]+[C60]− between Т = (240 and 310) K." @default.
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• W2000764134 date "2011-10-01" @default.
• W2000764134 modified "2023-09-25" @default.
• W2000764134 title "Thermodynamic properties of bis-(η6-cumene)chromium fulleride [(η6-PhCH(CH3)2)2Cr]+[C60]− over the range from Т→(0 to 310)K" @default.
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• W2000764134 doi "https://doi.org/10.1016/j.jct.2011.05.005" @default.
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