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- W2000770127 abstract "The free radical copolymerization of vinyl imidazole (VI) with γ-methacryloxypropyltrimethoxy silane (γ-MPS) by using azobisisobutyronitrile (AIBN) as an initiator was carried out in benzene at 68°C. The copolymer compositions at various monomer feeds were investigated by elemental analysis. The reactivity ratios of two monomers were determined by the Finemann-Ross method: r1(VI) = 0.22, r2 (γ-MPS) = 3.18. From these results, it could be concluded that silane-modified polyvinylimidazoles were random copolymers (0<r1r2<1). Thermal stability of decomposition of the copolymer increased with increasing the mole ratio of VI in the copolymer. Thermal decomposition of the copolymer was caused by the decomposition of the γ-MPS unit. However, thermal stability above 300°C and maximum thermal decomposition temperature increased with increasing the mole ratio of γ-MPS due to the crosslinking reaction of hydrolyzed γ-MPS unit. © 1995 John Wiley & Sons, Inc." @default.
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- W2000770127 date "1995-06-13" @default.
- W2000770127 modified "2023-10-16" @default.
- W2000770127 title "Copolymerization of the silane-modified polyvinylimidazole(1) as a metal corrosion inhibitor" @default.
- W2000770127 doi "https://doi.org/10.1002/app.1995.070561111" @default.
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