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• W2000770672 abstract "Nd 3+ -activated strontium lanthanum aluminate Sr1−xNdyLax−yMgxAl12−xO19 (ASL:Nd) crystals give efficient F43/2→I49/2 laser emission at 900 nm, whose properties depend on the x and y composition parameters. Based on high-resolution spectroscopy and emission decay, this paper demonstrates that the composition dependence of the laser emission is caused by the presence of two structural centers, C1 and C2, whose relative proportion in crystals is determined by composition parameter x. From the spectral data and crystal structure it is inferred that C2 center that prevails at low x, corresponds to a Nd3+ in a Sr2+ (2d) site of D3h local symmetry with no nearby Ln3+ (La3+ or Nd3+) ions. The C1 center lines, prevailing at large x parameter, which are broader and shift with composition, are composite lines of various structural centers of Nd3+ in a Sr2+ site with different occupancy of nearest-neighbor sites by Ln3+. The influence of the spectral and emission dynamics features of these centers on the laser properties is discussed and criteria for the selection of optimal composition is inferred." @default.
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• W2000770672 date "2004-09-02" @default.
• W2000770672 modified "2023-09-25" @default.
• W2000770672 title "Spectroscopic and structural properties of Nd3+ doped strontium lanthanum aluminate laser crystals" @default.
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• W2000770672 doi "https://doi.org/10.1063/1.1762709" @default.
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