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• W2000775600 abstract "The melting temperature T(M) of two series of dimeric (gemini) surfactants, the alkanediyl-alpha,omega-bis(dodecyl and hexadecyl dimethylammonium bromide), referred to as 12-s-12 and 16-s-16, respectively (s = carbon number of the alkanediyl spacer), and the Krafft temperature T(K) of 1 wt% aqueous solutions of these surfactants have been measured. The melting temperature of the solid surfactant increases with the carbon number m of the alkyl chain. For each surfactant series, T(M) goes through a maximum at s close to 5, irrespective of the value of m. For the 12-s-12 series, T(M) goes through a minimum at s = 10 to 12. At a constant value of s, the value of T(K) increases with m. The variations of T(M) and T(K) with s show some correlation, with T(K) decreasing when T(M) increases and vice versa. The results are discussed in relation to the solution properties of the investigated surfactants." @default.
• W2000775600 created "2016-06-24" @default.
• W2000775600 creator A5091037649 @default.
• W2000775600 date "2002-08-01" @default.
• W2000775600 modified "2023-09-25" @default.
• W2000775600 title "Alkanediyl-α,ω-bis(dimethylalkylammonium bromide) Surfactants: II. Krafft Temperature and Melting Temperature" @default.
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• W2000775600 doi "https://doi.org/10.1006/jcis.2002.8457" @default.
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